fluid
It doesn't matter if the fluid is new or not; you could still quite easily have boiled it if it wasn't a high quality dot 3 or 4. Granted, it doesn't sound like you really got up to temp to boil them, but it's a possibility.
From what you've said, I can imagine it being glazed pads from improper bedding of the pads/rotors... but how you can tell it's glazed, I have no idea.
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